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In The Stun Spore Detour, Ash Ketchum and Tracey Sketchit are made I'll by inhaling the Stun Spore or a Vileplume that was acting in self-defense over an accident, and Misty has to find Salveyo Weed to cure them, but only a Poliwag knows where to find them.
Misty manages to find a Poliwag and it leads her to the Salveyo Weed and after a minor battle with James and Meowth, leaves them with some of the weed to help Jessie.