Round Charm is a key item you can only obtain as a gift. When you successfully catch and record all Unova region Pokémon and show your Pokédex to Professor Juniper, she will gift it to the player. It increases the likelihood that your Pokémon will have eggs when placed in the Day Care Center.
While the exact percentage rate is unknown, tests have confirmed it to be between an average of 5-15 percent.
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