It made its debut in Two Degrees of Separation. When James opens his Poké Ball, Carnivine jumps out and bitess on James' head. James had originally caught Carnivine in the Great Marsh as a boy when it appeared to be quite injured, as mentioned in a flashback. Also Carnivine was used by Jessie for several contest in Sinnoh.
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|Bite||Dawn Of A New Era!|
|Bullet Seed||Gettin' Twiggy With It!|
|Bind||Arrival Of A Rival!|
|Vine Whip||Saving the World from Ruins!|
|+ indicates this Pokémon used this move recently.*|
- indicates this Pokémon normally can't use this move.