In BW062, it teamed up with Ash's Pikachu to stop the battle between the Kami Trio. Their combination of Thunderbolt and Thundershock stood well, but they were unable to win against them.
In BW069, it was used to battle Skyla's Swanna. Despite it's Thndershock attack being 4x super effective, Swanna shrugged it off. Scald the burned it, but it recovered with Aqua Ring, and then brutally defeated him with Hurricane and Brave Bird.