This Pansear belongs to Chili of the Striaton City Gym and made its first appearance in Triple Leaders, Team Threats!. It was the first of the three brother's Pokémon which Ash battled. It went up against Ash's Tepig and was defeated, despite Chili thinking he had the advantage because it was a Fire-type against a Fire-type and it was Ash's first battle with Tepig.
It was also seen in A Call for Brotherly Love! when Cilan battled with Chili, but Pansear ultimately lost. Chili angrily blames Pansear for their loss causing the two to break up their partnership until Cilan and his Pansage calmed them down and reconcile. Cilan also let his brother train his Pansear to learn Solar Beam which it did successfully? Later, it battled Ash's Oshawott and won due to Cilan helping Chili and Pansear train and the latter mastered Solar Beam as part of the training.
|Flamethrower||Triple Leaders, Team Threats!|
|Dig||Triple Leaders, Team Threats!|
|Fire Punch +||Triple Leaders, Team Threats!|
|Flame Charge +||A Call for Brotherly Love!|
|Fire Blast +||A Call for Brotherly Love!|
|Solar Beam +||A Call for Brotherly Love!|
|+ indicates this Pokémon used this move recently.*|
- indicates this Pokémon normally can't use this move.