Archie used Starmie when he was the Guile Hideout. He used his multiple Starmie to attack the Frontier Brains after he succeeded in capturing Jirachi. After the Starmie attacked, he made his escape without getting attacked due to the multiple Starmie attack the Frontier Brains. Archie also sent Starmie to battle the Pokédex Holders.
None of Starmie's moves are known.