|Friends:||Mairin, Astrid, Remo|
|First Appearance:||Pokémon: Mega Evolution Special I|
|Voice actor:|| Kenshō Ono (Japanese)|
Johnathan Silver (English)
Alain is a character who made his debut in the Pokémon special Mega Evolution I.
Alain is a Pokémon trainer with a goal to defeat every Mega Evolution that exists. He wears a band on his wrist which allows him to Mega Evolve his Charizard into Mega Charizard X. He is shown to be compassionate to young Pokémon trainers such as Mairin, much like Ash Ketchum. However unlike Ash, Alain is shown to be older with a more mature and serious nature when it comes to battle and prefers to travel alone.
|Pokémon Season 18|
|Main characters||Ash Ketchum - Bonnie - Clemont - James - Jessie - Monsieur Pierre - Nurse Joy - Officer Jenny - Professor Sycamore - Serena - Shauna - Tierno - Trevor|
|Main character's Pokémon||Ash's Fletchinder - Ash's Frogadier - Ash's Hawlucha - Ash's Pikachu - Ash's Sliggoo|
Serena's Fennekin - Serena's Pancham
Clemont's Bunnelby - Clemont's Chespin - Clemont's Dedenne - Clemont's Heliolisk - Clemont's Luxray - Clemont's Magnemite - Clemont's Magneton
James' Inkay - Jessie's Pumpkaboo - Jessie's Wobbuffet - Team Rocket's Meowth
Shauna's Bulbasaur - Shauna's Flabébé
Tierno's Hitmontop - Tierno's Ludicolo - Tierno's Politoed - Tierno's Raichu - Tierno's Wartortle
|Supporting characters||Alain - Aria - Armelle - Berry - Blanche - Carl - Clarisse - Clembot - Coumarine City's Gym referee - Dr. White - Grace - Meyer - Nini - Olympia - Pokémon Hunter - Ramos - Saizo - Sanpei - Valerie - Volt - Yashio|